Get your special meter (meter underneath the Superstar's name) full, then do the following:
Booker T's Book-End: Grapple your opponent and press Select.
Booker T's Scissors Kick: Grapple your opponent and press Select.
Booker T's Scissors Kick: Kick on your opponent, then press Select.
Chavo Guererro's (Unknown name): Grapple your opponent and press Select.
Chavo Guererro's Frog Splash: Climb to the top rope and press Select.
Chris Benoit's Crippler Crossface: Put your opponent on his stomach, then go to the head and press Select.
Chris Benoit's Diving Headbutt: Climb to the top rope and press Select. Note: Make sure your opponent is in range.
Chris Benoit's Rolling German Suplexs: Grapple your opponent from behind and press Select.
Chris Jericho's The Walls of Jericho: Put your opponent on his back, then go to feet and press Select.
Chris Jericho's German Suplex: Grapple your opponent from behind and press Select.
Christian's Unprettier: Grapple your opponent from behind and press Select.
Eddie Guererro's Frog Splash: Climb to the top rope and press Select. Note: Make sure your opponent is in range.
Eddie Guererro's Three Amigos: Grapple your opponent and press Select.
Edge's Edgecution: Grapple your opponent and press Select.
John Cena's F-U: Grapple your opponent(does not have to be stunned) and press Select.
Kane's Chokeslam: Grapple your opponent and press Select.
Kurt Angle's Angle Slam: Grapple your opponent and press Select.
Kurt Angle's Ankle Lock: Put your opponent on his stomach, then go to the feet and press Select.
Kurt Angle's Rolling German Suplexes: Grapple your opponent from behind and press Select.
Randy Orton's RKO: Grapple your opponent and press Select.
Randy Orton's Running RKO: Run to your opponent and press Select.
Rey Mysterio's 619: Get your special bar filled, then press Select while in front of your opponent.
Rey Mysterio's Bulldog: Grapple your opponent and press Select.
Rey Mysterio's Running Bulldog: Run to your opponent and press Select.
Rob Van Dam's 5 Star Frog Splash: Climb to the top rope and press Select. Note: Make sure your opponent is in range.
Rob Van Dam's Van Daminator: Grapple your opponent and press Select.
Shawn Micheals' Sweet Chin Music: Press Select.
The Undertaker's Tombsstone: Grapple your opponent and press Select.
The Undertaker's Tombstone Piledriver: Grapple your opponent and press Select.
The Undertaker's Last Ride: Kick on your opponent, then press Select.
Triple H's Pedigree: Grapple your opponent and press Select.
Super Suplex: Pull your opponent (grapple him, then press R + Left or Right ) to a corner. Then, grapple him and press Up.